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chiral synthesis

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  • Chiral pool synthesis — is a strategy that aims to improve the efficiency of chiral synthesis. It starts the organic synthesis of a complex enantiopure chemical compound from a stock of readily available enantiopure substances. Common chiral starting materials include… …   Wikipedia

  • Chiral resolution — in stereochemistry is a process for the separation of racemic compounds into their enantiomers.[1] It is an important tool in the production of optically active drugs. Other terms with the same meaning are optical resolution and mechanical… …   Wikipedia

  • Chiral Lewis acid — Chiral Lewis acids (CLAs) are a novel class of Lewis acid catalyst used in enantioselective asymmetric synthesis reactions which produce optically active products from optically inactive or impure starting materials. This type of preferential… …   Wikipedia

  • Chiral column chromatography — is a variant of column chromatography in which the stationary phase contains a single enantiomer of a chiral compound rather than being achiral. The two enantiomers of the same analyte compound differ in affinity to the single enantiomer… …   Wikipedia

  • Chiral ligand — In chemistry a chiral ligand is a specially adapted ligand used for asymmetric synthesis. This ligand is an enantiopure organic compound which combines with a metal center by chelation to form an asymmetric catalyst. This catalyst engages in a… …   Wikipedia

  • Chiral auxiliary — A chiral auxiliary is a chemical compound or unit that is temporarily incorporated into an organic synthesis so that it can be carried out asymmetrically with the selective formation of one of two enantiomers[1][2] . Chiral auxiliaries are… …   Wikipedia

  • Chiral derivatizing agent — A chiral derivatizing agent (CDA) also known as a chiral resolving reagent, is a chiral auxiliary which can convert a mixture of enantiomers into diastereomers in order to analyse the quantities of each enantiomer present within the mix. In NMR… …   Wikipedia

  • Enantioselective synthesis — Enantioselective synthesis: Sharpless epoxidation Enantioselective synthesis, also called chiral synthesis, asymmetric synthesis or stereoselective synthesis, is organic synthesis that introduces one or more new and desired elements of… …   Wikipedia

  • Asymmetric synthesis — Asymmetric synthesis, also called chiral synthesis, enantioselective synthesis or stereoselective synthesis, is organic synthesis which introduces one or more new and desired elements of chirality. [GoldBookRef|title=asymmetric synthesis| file =… …   Wikipedia

  • Galanthamine total synthesis — ; 2006; 106(1) pp 116 133; (Review) DOI|10.1021/cr040415t] The natural source of galantamine are certain species of daffodil and because these species are scarce and because the isolation of galanthamine from daffodil is expensive (a 1996 figure… …   Wikipedia

  • Organic synthesis — This article is about artificial synthesis of organic compounds. For the journal Organic Syntheses, see Organic Syntheses. For synthesis in organisms, see Biosynthesis. Organic synthesis is a special branch of chemical synthesis and is concerned… …   Wikipedia

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